Unraveling the mechanism of electrospray ionization.
نویسندگان
چکیده
Electrospray ionization (ESI) generates intact gas-phase ions from analytes in solution for mass spectrometric investigations. ESI can proceed via different mechanisms. Low molecular weight analytes follow the ion evaporation model (IEM), whereas the charged residue model (CRM) applies to large globular species. A chain ejection model (CEM) has been proposed for disordered polymers.
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ورودعنوان ژورنال:
- Analytical chemistry
دوره 85 1 شماره
صفحات -
تاریخ انتشار 2013